Download e-book for iPad: Alkaline-Earth Metal Compounds: Oddities and Applications by Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder

By Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder (eds.)

ISBN-10: 3642362699

ISBN-13: 9783642362699

ISBN-10: 3642362702

ISBN-13: 9783642362705

The sequence subject matters in Organometallic Chemistry provides serious overviews of study leads to organometallic chemistry. As our figuring out of organometallic constitution, houses and mechanisms raises, new methods are opened for the layout of organometallic compounds and reactions adapted to the wishes of such different parts as natural synthesis, scientific learn, biology and fabrics technological know-how. therefore the scope of insurance encompasses a extensive variety of issues in natural and utilized organometallic chemistry, the place new breakthroughs are being accomplished which are of importance to a bigger clinical viewers. the person volumes of subject matters in Organometallic Chemistry are thematic. evaluate articles are more often than not invited by way of the amount editors.

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Additional resources for Alkaline-Earth Metal Compounds: Oddities and Applications

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1 Ether Degradation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Directed ortho-Calciations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Conclusion and Perspective . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Acknowledgments The authors gratefully acknowledge support from the National Science Foundation (CHE 0753807) and Syracuse University. References 1. Crimmin MR, Barrett AGM, Hill MS, Hitchcock PB, Procopiou PA (2008) Organometallics 27:497 2. Crimmin MR, Casely IJ, Hill MS (2005) J Am Chem Soc 127:2042 3. He X, Hurley E, Noll BC, Henderson KW (2008) Organometallics 27:3094 4. Datta S, Roesky PW, Blechert S (2007) Organometallics 26:4392 5. Datta S, Gamer MT, Roesky PW (2008) Organometallics 27:1207 6.

Use of the alkaline-earth bis(bis(trimethylsilyl)amides in conjunction with benzylic lithium reagents has afforded a pathway to the preparation in high yields of alkaline-earth organometallics in the form of benzylates [144, 146, 147] which are the starting materials necessary for organoelimination reactions leading to di- and triphenylmethanides (see above) (Fig. 15) [145]. 9 Conclusions The rapid development of alkaline-earth organometallic and metal organic chemistry has been made possible by the examination and often modifications of established synthetic strategies, in addition to the exploration of alternative Heavy Alkaline-Earth Metal Organometallic and Metal Organic Chemistry.

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Alkaline-Earth Metal Compounds: Oddities and Applications by Ana Torvisco, Karin Ruhlandt-Senge (auth.), Sjoerd Harder (eds.)


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